自然指数新星榜出炉,南科大化学系表现亮眼 2015年5月1-2016年4月30日,化学系共发表19篇文章(AC),加权文章总值(WFC)为12.98。自然指数排名对新型学校的提升和进步具有非常重要的意义。
张绪穆教授做客深圳中学分享讲座 2016年11月23日下午,我校化学系系主任张绪穆教授做客深圳中学,带来了题为《由灵感到书架,由书架到货架》的大型科普演讲。
致敬时代深士:化学系主任张绪穆获此殊荣 本次评选,共有82家政府部门、社会机构、行业协会、代表企业等参与推举,经过评委会的慎重票选和网络上近200万人次的投票,最终诞生6名“2016时代深士”。
第六届岭南有机化学论坛在南科大举行 2016年11月5日至6日,由广东省化学会和南方科技大学共同主办,以“有机化学”为主题的第六届岭南有机化学论坛在南方科技大学举行。来自全国8个省市的30所高校、科研所的学术领袖与青年学
国内首个诺奖得主命名研究机构深圳格拉布斯研究院揭牌 016年10月12日,由南方科技大学与诺贝尔化学奖得主罗伯特•格拉布斯(Robert H. Grubbs)合作建立的深圳格拉布斯研究院在深圳市民中心隆重揭牌。
许宗祥课题组在钙钛矿太阳电池空穴传输材料取得进展 论文在Nano Energy(IF=11.553)在线发表。论文详细介绍了新型金属酞菁功能材料分子设计与太阳电池器件应用研究的成果。
蒋伟课题组发明检测地下水中持久性污染物简易方法 我校化学系蒋伟课题组提出了地下水中持久性污染物——1,4-二氧六环的简便检测方法。该研究成果在线发表在化学类顶级期刊JACS上(IF=13.038)。

刘心元

副教授

化学系

0755-88018314

liuxy@sustc.edu.cn

研究方向
非活性烯烃和炔烃的催化功能化等


2001年在安徽师范大学化学系获学士学位,2004年在中国科学院上海有机化学研究所与安徽师范大学联合培养获硕士学位,师从王绍武教授和朱仕正研究员;2010年在香港大学获哲学博士学位,师从支志明院士。2010年4月至20129月先后在香港大学和美国The Scripps Research Institute从事博士后研究。20129月加入南方科技大学化学系。曾获得香港大学2009-2010年杰出研究生奖,入选深圳市海外高层次“孔雀计划”B类人才等。研究方向是围绕非活性烯烃和炔烃的不对称官能团化开展工作。以第一作者或通讯作者在国内外期刊上共发表SCI检索论文40篇如J. Am. Chem. Soc. (3篇)、Angew. Chem. Int. Ed. (9篇)、Nature Commun. (1篇)、ACS Catal. (3篇)、Chem. Commun. (4篇)、Org. Lett. (8篇)及 Chem. Eur. J. (3篇)等。其中9篇论文被Synfacts亮点评述(Synfacts 2016, 12, 86; 2015, 11, 1029; 2014, 10, 1281; 2014, 10, 1272; 2014, 10, 754; 2014, 10, 530; 2013, 9, 1251; 2009, 5, 600; 2009, 5, 1363.); 2篇论文受邀收录于Emerging Investigators专刊 (Chem. Commun., 2016, 52, 9052; Org. Chem. Front., 2016, 3, 324.);4篇论文被选为封面和插图文章;2篇论文被选为热点文章;2篇论文被Organic Chemistry Portal(有机化学门户)亮点报道;1Org. Lett.论文在2009年被选为该杂志三年内发表的引用次数最多的20篇文章之一;1篇论文在有机化学亮点介绍 (Chin. J. Org. Chem. 2015, 35, 1802.)。引用次数达1500次;其中有三篇论文单篇引用次数达129次。

2012年底在南方科技大学开展独立的科研工作,迅速建立科研团队。目前主要围绕均相和非均相(金属框架)催化剂的设计与他们组成协同催化剂;不对称自由基化学。在短短三年时间里积累了丰富的研究经验并取得了多项创新性成果,以通讯作者身份在高影响力期刊上发表29篇具有重要学术影响力的论文,如J. Am. Chem. Soc. (3篇)、Angew. Chem. Int. Ed. (6篇)、Nature Commun. (1篇)、ACS Catal. (3篇)、Chem. Commun. (4篇)、Org. Lett. (5篇)及 Chem. Eur. J. (3篇)等。其中七篇论文分别被Synfacts专题评述 (Synfacts 2016, 12, 86; 2015, 11, 1029; 2014, 10, 1281; 2014, 10, 1272; 2014, 10, 754; 2014, 10, 530; 2013, 9, 1251.);1篇论文被Organic Chemistry Portal(有机化学门户)亮点报道;1篇论文在有机化学亮点介绍 (Chin. J. Org. Chem. 2015, 35, 1802.)。1篇论文Angew. Chem. Int. Ed. (2015, 54, 4041.)被选为该杂志的封面文章;同时,2013年发表的论文Chem. Commun. (2013, 49, 7681.)被选为该杂志的封面文章,同时被选为热点文章。最近2篇论文受邀收录于Emerging Investigators专刊 (Chem. Commun., 2016, 52, 9052; Org. Chem. Front., 2016, 3, 324.)。主持1项国家自然科学基金面上项目,1项国家自然科学基金青年基金项目,1项深圳市孔雀计划技术创新项目,2项深圳市基础项目,同时作为主要参与人承担国家科技部973项目及深圳市孔雀团队项目。在国内外学术会议上或著名大学进行了十多次交流报告。



2011,香港大学杰出研究生奖

◆ 2013,深圳市海外高层次人才“孔雀计划”入选者

◆ 非活性烯烃和炔烃的催化功能化

◆ 不对称自由基化学

◆ 均相和非均相催化剂的设计与应用

◆ 有机氟化学的研究

1. 973 项目,2013CB834800、25 万、主要参与人; 2015.1‐2017.8

2. 国家自然科学基金委面上项目,78 万、项目负责人;2016.1‐2019.12

3. 国家自然科学基金委青年基金,25 万、项目负责人;2014.1‐2016.12

4. 深圳市孔雀创新启动经费项目,570 万、项目负责人;2013.12‐2016.12

5. 深圳市孔雀创新团队资助项目,200 万、项目子课题;2015.8‐2020.8

6. 深圳市孔雀创新资助项目,80 万、项目负责人;2015.8‐2017.8

7. 深圳市基础科研项目,50 万、项目负责人;2015.8‐2017.8

8. 深圳市基础科研项目,10 万、项目负责人;2013.8‐2015.8

9. 南方科技大学副校长基金,50 万、项目负责人;2015.1‐2015.12

1.   Jin-Shun Lin, Xiao-Yang Dong, Tao-Tao Li, Na-Chuan Jiang, Bin Tan, and Xin-Yuan Liu* A Dual-Catalytic Strategy to Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes J. Am. Chem. Soc. 2016, 138, 9357.

2.   Zhi-Jia Fang, Sheng-Cai Zheng, Zhen Guo, Jing-Yao Guo, Bin Tan,* Xin-Yuan Liu*, Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation Angew. Chem. Int. Ed. 2015, 54, 9528.

Highlighted in Synfacts, 2015, 11, 1029.

3.   Jin-Shun Lin, Peng Yu, Lin Huang, Pan Zhang, Bin Tan,* Xin-Yuan Liu*, Brønsted Acid-Catalyzed Asymmetric Hydroamination of Alkenes: Synthesis of Pyrrolidines Bearing a Tetrasubstituted Carbon Stereocenter Angew. Chem. Int. Ed. 2015, 54, 7847.

Highlighted in Chin. J. Org. Chem., 2015, 35, 1802.

4. Peng Yu, Sheng-Cai Zheng, Ning-Yuan Yang, Bin Tan,* Xin-Yuan Liu*,Phosphine-Catalyzed Remote β-C-H Functionalization of Amine Triggered by Trifluoromethylation of Alkene: One-Pot Synthesis of Bistrifluoromethylated Enamides and Oxazoles, Angew. Chem. Int. Ed. 2015, 54, 4041.

Selected as Cover Picture.

5.  Peng Yu, Jin-Shun Lin, Lei Li, Sheng-Cai Zheng, Ya-Ping Xiong, Li-Jiao Zhao, Bin Tan*, and Xin-Yuan Liu* “Enantioselective C-H Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated Alkene” Angew. Chem. Int. Ed. 2014, 53, 11890.

Highlighted in Synfacts, 2014, 10, 1281.

6.   Ji-Wei Zhang, Jin-Hui Xu, Dao-Juan Cheng, Chuan Shi, Xin-Yuan Liu*, Bin Tan,* Discovery and Enantiocontrol of Axially Chiral Urazoles via Organocatalytic Tyrosine Click Reaction Nature Commun. 2016, 7, 10677.

7.   Jian Zhang, Shao-Xia Lin, Dao-Juan Cheng, Xin-Yuan Liu*, Bin Tan,* Phosphoric Acid-Catalyzed Asymmetric Classic Passerini Reaction J. Am. Chem. Soc. 2015, 137, 14039.

Highlighted in Synfacts, 2016, 12, 86.

8.  Ye-Hui Chen, Dao-Juan Cheng, Jian Zhang, Yong Wang, Xin-Yuan Liu*, Bin Tan,* Atroposelective Synthesis of Axially Chiral Biaryldiols via Organocatalytic Arylation of 2‑Naphthols J. Am. Chem. Soc. 2015, 137, 15062.

9.  Ming-Yue Wu, Wei-Wei He, Xin-Yuan Liu*, Bin Tan,* Asymmetric Construction of Spirooxindoles via Organocatalytic Multicomponent Reactions of Diazooxindoles Angew. Chem. Int. Ed. 2015, 54, 9409.

10.  Dao-Juan Cheng, Liang Yan, Shi-Kai Tian,* Ming-Yue Wu, Lu-Xin Wang, Zi-Li Fan, Sheng-Cai Zheng, Xin-Yuan Liu,* and Bin Tan* “Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid” Angew. Chem. Int. Ed. 2014, 53, 3684.

Highlighted in Synfacts, 2014, 10, 530.

11.  Ning-Yuan Yang, Zhong-Liang Li, Liu Ye, Bin Tan and Xin-Yuan Liu* Organic base-catalysed solvent-tuned chemoselective carbotrifluoromethylation and oxytrifluoromethylation of unactivated alkenes Chem. Commun., 2016, 52, 9052.

From themed collection 2016 Emerging Investigators by Chem. Commun.

12.  Xiao-Long Yu, Liping Kuang, Su Chen, Xiao-Long Zhu, Zhong-Liang Li, Bin Tan, and Xin-Yuan Liu* Counteranion-Controlled Unprecedented Diastereo- and Enantioselective Tandem Povarov Reaction for Construction of Bioactive Octahydro-dipyrroloquinolines ACS Cat. 2016, in press.

13.  Na Wang, Sheng-Cai Zheng, Lin-Lin Zhang, Zhen Guo* and Xin-Yuan Liu* Nickel(0)-Catalyzed Denitrogenative Transannulation of Triazoles with Alkynes: Mechanistic Insights of Chemical Reactivity, Regio- and Enantioselectivity from Density Functional Theory and Experiment ACS Cat. 2016, 6, 3496.

14.  Taotao Li, Peng Yu, Jin-Shun Lin, Yonggang Zhi,* and Xin-Yuan Liu* Copper-Catalyzed Redox-Triggered Remote CH Functionalization: Highly Selective Formation of C-CF3 and C-O Bonds Chin. J. Chem. 2016, 34, 490.

Invited paper for the Special Issue of “Trifluoromethylation and Trifluoromethythiolation Reactions”

15.  Can-Liang Ma, Xiao-Hua Li, Xiao-Long Yu, Xiao-Long Zhu, Yong-Zhou Hu, Xiao-Wu Dong,* Bin Tan* and Xin-Yuan Liu* Gold-catalyzed tandem synthesis of bioactive spiro-dipyrroloquinolines and its application in the one-step synthesis of incargranine B aglycone and seneciobipyrrolidine (I) Org. Chem. Front. 2016, 3, 324.

From themed collection 2015 Emerging Investigators by OCF.

16.  Lin Huang, Jin-Shun Lin, Bin Tan,* Xin-Yuan Liu*, Alkene Trifluoromethylation-Initiated Remote α-Azidation of Carbonyl Compounds toward Trifluoromethyl γ-Lactam and Spirobenzofuranone-lactam ACS Cat. 2015, 5, 2826-2831.

17.  Lin Huang, Sheng-Cai Zheng, Bin Tan,* Xin-Yuan Liu*, Metal-Free Direct 1,6- and 1,2-Difunctionalization Triggered by Radical Trifluoromethylation of Alkenes Org. Lett. 2015, 17, 1589-1592.

18.  Lin Huang, Sheng-Cai Zheng, Bin Tan,* Xin-Yuan Liu*, Trifluoromethylation-Initiated Remote Cross-Coupling of Carbonyl Compounds to Form Carbon–Heteroatom/Carbon Bonds Chem. Eur. J. 2015, 21, 6718.

19.  Can-Liang Ma, Xiao-Long Yu, Xiao-Long Zhu, Yong-Zhou Hu, Xiao-Wu Dong, Bin Tan*, and Xin-Yuan Liu* “Platinum-Catalyzed Tandem Cyclization Reaction to Multiply Substituted Indolines under Microwave-Assisted Conditions” Adv. Synth. Catal. 2015, 357,569.

20.  Lei Li, Jing-Yao Guo, Xing-Guo Liu, Su Chen, Yong Wang, Bin Tan*, and Xin-Yuan Liu*Amide Groups Switch Selectivity: C-H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation” Org. Lett., 2014, 16, 6032.

21.  Jin-Shun Lin, Xiang-Geng Liu, Xiao-Long Zhu, Bin Tan,* and Xin-Yuan Liu* “Copper-Catalyzed Aminotrifluoromethylation of Unactivated Alkenes with TMSCF3: Construction of Trifluoromethylated Azaheterocycles” J. Org. Chem. 2014, 79, 7084.

22.  Xing-Li Zhu, Jin-Hui Xu, Dao-Juan Cheng, Li-Jiao Zhao, Xin-Yuan Liu* and Bin Tan* “In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles” Org. Lett. 2014, 16, 2192.

Highlighted in Synfacts, 2014, 10, 754.

23.  Ya-Ping Xiong, Ming-Yue Wu, Xiang-Yu Zhang, Can-Liang Ma, Lin Huang, Li-Jiao Zhao, Bin Tan* and Xin-Yuan Liu* “Direct Access to α-CF3-enones via Efficient Copper-Catalyzed Trifluoromethylation of Meyer-Schuster Rearrangement” Org. Lett. 2014, 16, 1000.

This work is highlighted on the website http:// http://www.organic-chemistry.org/abstracts/lit4/389.shtm

24.  Lei Li, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Bin Tan* and Xin-Yuan Liu* “Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles” Org. Lett. 2014, 16, 504.

25.  Jin-Shun Lin, Ya-Ping Xiong, Can-Liang Ma, Li-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu* “Efficient Copper-Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen-Based Nucleophiles” Chem. Eur. J. 2014, 20, 1332.

26.  Tao Liu, Da-Qiang Li, Si-Yu Wang Yong-Zhou Hu, Xiao-Wu Dong,* Xin-Yuan Liu,* and Chi-Ming Che “Straightforward Installation of Carbon-Halogen, Carbon-Oxygen and Carbon-Carbon Bonds within Metal–Organic Frameworks via Direct C-H Functionalization” Chem. Commun., 2014, 50,13261.

   Highlighted in Synfacts, 2014, 10, 1272.

27. Tao Liu, Jin-Xin Che, Yong-Zhou Hu, Xiao-Wu Dong,* Xin-Yuan Liu,* Chi-Ming Che “Alkenyl/thiol-derived Metal–Organic Frameworks via Post-Synthetic Modification for Effective Mercury Adsorption” Chem. Eur. J. 2014, 20,14090.

 

28. Xiao-Wu Dong, Tao Liu, Yong-Zhou Hu*, Xin-Yuan Liu*, Chi-Ming Che. Urea Postmodified in Metal-Organic Framework as Catalytically Active Hydrogen-Bond-Donating Heterogeneous Catalyst Chem. Commun., 2013, 49, 7681.

  Highlighted with a front cover in Chem. Commun.;

  Selected as HOT Chem. Comm. articles for May;

  Highlighted in Synfacts, 2013, 9, 1251.

 

29. Gaosheng Yang,* Chongrong Luo, Xiaolong Mu, Tingting Wang and Xin-Yuan Liu*, Highly efficient enantioselective three-component synthesis of 2-amino-4H-chromenes catalysed by chiral tertiary amine-thioureas Chem. Commun. 2012, 48, 5880-5882.

 

Graduate & Postdoctoral Publications

1. Xin-Yuan Liu, Ya-Ping Xiao, Fung-Ming Siu, Li-Chen Ni, Yong Chen, Lin Wang, and Chi-Ming Che*, “Highly regio-, diastereo- and enantioselective one-pot gold/chiral Brønsted acid-catalysed cascade synthesis of bioactive diversely substituted tetrahydroquinolines” Org. Biomol. Chem. 2012, 10, 7208-7219.

 

2. Xin-Yuan Liu,[+] Zhen Guo,[+] Sijia Dong,[+] Xiao-Hua Li, and Chi-Ming Che*, “Highly efficient and diastereoselective gold(I)-catalyzed synthesis of tertiary amines from secondary amines and alkynes: substrate scope and mechanical insights” Chem. Eur. J. 2011, 17, 12932-12945. [+]denotes equal contribution

 

3. Ya-Ping Xiao,[+] Xin-Yuan Liu,[+] and Chi-Ming Che*, “Efficient gold(I)-catalyzed direct intramolecular hydroalkylation of unactivated alkenes with simple α-ketones” Angew. Chem. Int. Ed. 2011, 50, 4937-4941. [+]denotes equal contribution

 

4. Xin-Yuan Liu, Chi-Ming Che*, “Highly enantioselective synthesis of chiral secondary amines by gold(I)/chiral Brønsted acid-catalyzed tandem intermolecular hydroamination and transfer hydrogenation reactions” Org. Lett. 2009, 11, 4204-4207.

  Selected by the Editorial Board of SYNFACTS and published in SYNFACTS issue  12/09.

 

5. Xin-Yuan Liu, Chi-Ming Che*, “Highly efficient and regioselective platinum(II)-catalyzed tandem synthesis of multiply substituted indolines and tetrahydroquinolines” Angew. Chem. Int. Ed. 2009, 48, 2367-2371.

   Selected by the Editorial Board of SYNFACTS and published in SYNFACTS  

   issue 06/09.

 

6. Xin-Yuan Liu, Chi-Ming Che*, “A highly efficient and selective AuI-catalyzed tandem synthesis of diversely substituted pyrrolo[1,2-α]quinolines in aqueous medium” Angew. Chem. Int. Ed. 2008, 47, 3805-3810.

 

7. Xin-Yuan Liu, Pan Ding, Jie-Sheng Huang, Chi-Ming Che*, “Synthesis of substituted 1,2-dihydroquinolines and quinolines from aromatic amines and alkynes by gold(I)-catalyzed tandem hydroamination-hydroarylation under microwave-assisted conditions” Org. Lett. 2007, 9, 2645-2648.

 Selected on the ACS Publications website in 2009 as Top 20 most-cited articles published in the last three years.

 

8. Xin-Yuan Liu, Cheng-Hui Li, Chi-Ming Che*, “Phosphine gold(I)-catalyzed hydroamination of alkenes under thermal and microwave-assisted conditions” Org. Lett. 2006, 8, 2707-2710.

Featured on the ACS Publications website as one of “Organic Letters' Hot Papers” based on citation data obtained from Thomson ISI.

Highlighted on the website http://www.organic-chemistry.org/Highlights/2007/15August.shtm

Presentations:

1. 2012.10.29 , 华南理工大学邀请报告“ Gold(I)/Platinum(II)-Catalyzed Hydroamination of Alkenes and Alkynes and Related Tandem Reactions”

2. 2012.12.19, 温州大学邀请报告“Gold(I)/Platinum(II)-Catalyzed Hydroamination of Alkenes and Alkynes and Related Tandem Reactions”

3. 2013.1.9 , 合肥工业大学邀请报告“ Gold(I)/Platinum(II)-Catalyzed Hydroamination of Alkenes and Alkynes and Related Tandem Reactions”

4. 2014.8.22 , 中国化学会第十三届全国氟化学会议报告“ Radical

trifluoromethylation-triggered unactivated alkene and remote C-H bond functionalization”

5. 2014.10.19,中国化学会全国第十一届有机合成化学学术研讨会报告“Radical trifluoromethylation-triggered unactivated alkene and remote C-H bond functionalization”

6. 2014.11.2,第十二届江淮有机化学论坛报告“Remote C-H bond functionalization Triggered by radical trifluoromethylation of unactivated alkenes”

7. 2014.11.15,第四届岭南有机化学论坛报告“Radical trifluoromethylation-triggered unactivated alkene and remote C-H bond functionalization”

8. 2015.1.3,2015 年汕头大学973 年终汇报报告“Development and Synthesis of Heterogeneous MOF Chiral Catalysts”

9. 2015.7.30,中国化学会第九届全国有机化学学术会议报告“非活性烯烃和炔烃参与的不对称官能团化”

10. 2015.10.17, 华南前沿合成化学高端论坛报告“ Remote C-H Bond Functionalization Triggered by Radical Addition of Unactivated Alkenes and Alkynes”

Presentations:

1. 2012.10.29 , 华南理工大学邀请报告“ Gold(I)/Platinum(II)-Catalyzed Hydroamination of Alkenes and Alkynes and Related Tandem Reactions”

2. 2012.12.19, 温州大学邀请报告“Gold(I)/Platinum(II)-Catalyzed Hydroamination of Alkenes and Alkynes and Related Tandem Reactions”

3. 2013.1.9 , 合肥工业大学邀请报告“ Gold(I)/Platinum(II)-Catalyzed Hydroamination of Alkenes and Alkynes and Related Tandem Reactions”

4. 2014.8.22 , 中国化学会第十三届全国氟化学会议报告“ Radical

trifluoromethylation-triggered unactivated alkene and remote C-H bond functionalization”

5. 2014.10.19,中国化学会全国第十一届有机合成化学学术研讨会报告“Radical trifluoromethylation-triggered unactivated alkene and remote C-H bond functionalization”

6. 2014.11.2,第十二届江淮有机化学论坛报告“Remote C-H bond functionalization Triggered by radical trifluoromethylation of unactivated alkenes”

7. 2014.11.15,第四届岭南有机化学论坛报告“Radical trifluoromethylation-triggered unactivated alkene and remote C-H bond functionalization”

8. 2015.1.3,2015 年汕头大学973 年终汇报报告“Development and Synthesis of Heterogeneous MOF Chiral Catalysts”

9. 2015.7.30,中国化学会第九届全国有机化学学术会议报告“非活性烯烃和炔烃参与的不对称官能团化”

10. 2015.10.17, 华南前沿合成化学高端论坛报告“ Remote C-H Bond Functionalization Triggered by Radical Addition of Unactivated Alkenes and Alkynes”

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