自然指数新星榜出炉,南科大化学系表现亮眼 2015年5月1-2016年4月30日,化学系共发表19篇文章(AC),加权文章总值(WFC)为12.98。自然指数排名对新型学校的提升和进步具有非常重要的意义。
张绪穆教授做客深圳中学分享讲座 2016年11月23日下午,我校化学系系主任张绪穆教授做客深圳中学,带来了题为《由灵感到书架,由书架到货架》的大型科普演讲。
致敬时代深士:化学系主任张绪穆获此殊荣 本次评选,共有82家政府部门、社会机构、行业协会、代表企业等参与推举,经过评委会的慎重票选和网络上近200万人次的投票,最终诞生6名“2016时代深士”。
第六届岭南有机化学论坛在南科大举行 2016年11月5日至6日,由广东省化学会和南方科技大学共同主办,以“有机化学”为主题的第六届岭南有机化学论坛在南方科技大学举行。来自全国8个省市的30所高校、科研所的学术领袖与青年学
国内首个诺奖得主命名研究机构深圳格拉布斯研究院揭牌 016年10月12日,由南方科技大学与诺贝尔化学奖得主罗伯特•格拉布斯(Robert H. Grubbs)合作建立的深圳格拉布斯研究院在深圳市民中心隆重揭牌。
许宗祥课题组在钙钛矿太阳电池空穴传输材料取得进展 论文在Nano Energy(IF=11.553)在线发表。论文详细介绍了新型金属酞菁功能材料分子设计与太阳电池器件应用研究的成果。
蒋伟课题组发明检测地下水中持久性污染物简易方法 我校化学系蒋伟课题组提出了地下水中持久性污染物——1,4-二氧六环的简便检测方法。该研究成果在线发表在化学类顶级期刊JACS上(IF=13.038)。

谭斌

副教授

化学系

0755-88018315

tanb@sustc.edu.cn

研究方向
​核心骨架结构导向的催化不对称合成 等

       2005年硕士毕业于厦门大学化学系。 2006年开始在新加坡南洋理工大学化学与生物化学系钟国富教授的指导下从事新型手性有机催化剂的设计及不对称多米诺反应的研究,于2010 3月获得博士学位。20103月至2012 9月,有幸在有机小分子催化领域的发源地--美国斯克普斯研究所 The Scripps Research Institute),师从Barbas教授继续在此领域从事博士后研究。

       到目前为止,以第一作者或通讯作者身份已经发表包括1Nature Chemistry1Nature Communications, 4J. Am. Chem. Soc. 10Angew. Chem. Int. Ed. 在内的近40篇国外核心期刊SCI检索论文,总被引次数超过2500次。多篇论文被多篇文章被不同国际杂志重点评述或被选为封面文章。

       2012年9月受聘为南方科技大学化学系。从20138月在教学实验室开始,在不到三年的时间里,以通讯作者身份,在核心骨架导向的不对称催化,自由基化学以及协同催化领域发表高水平研究论文20篇,其中2J. Am. Chem. Soc.1Nature Communications, 7Angew. Chem. Int. Ed.,以及2ACS catalysis,还有多篇高水平研究论文正在审稿和准备之中。

2012年,中组部第四批“青年千人计划”入选者

2013年,深圳市海外高层次人才“孔雀计划”B类入选者

◆ 核心骨架结构导向的催化不对称合成    

◆ 有机催化不对称多组分反应

◆ 金属与有机催化协同的催化体系应用   

◆ 手性药物的开发和天然产物策略全合成

1.    国家“青年千人计划“研究基金+广东省配套经费(250万);

2.    孔雀计划配套科研启动经费(500 + 100 )

核心骨架结构导向的催化不对称合成;

3.    国家自然科学基金委面上项目(80万)

有机催化不对称合成联芳基轴手性化合物;

4.    国家自然科学基金委青年基金项目(25)

不对称合成具有重要生物活性3,3′-四氢吡咯螺羟吲哚骨架结构;

5.    深圳市科技创新委员会基础研究项目(10万)

四氢吡咯螺羟吲哚衍生物的设计和催化不对称合成以及抗癌活性的研究;

6.    深圳市科技创新委员会基础研究项目(30万)

基于重氮吲哚酮的催化不对称合成及其产物的抗癌活性研究;

7.    深圳市科技创新委员会“孔雀团队”项目(200万)

重大药物的绿色制备

代表性研究成果:(独立工作以前)

1.      Tan, B.; Candeias, N.; Barbas III, C. F. Construction of Bispirooxindoles Containing three Quaternary Stereocentres in a Cascade Using a Single Multifunctional Organocatalyst. Nature Chem. 2011, 3, 473-477.

2.      Tan. B.; Toda N; Barbas III, C. F. Organocatalytic Amidation and Esterification of Aldehydes with Activating Reagents by a Cross-coupling Strategy. Angew. Chem. Int. Ed. 2012, 51, 12538-12541.

3.      Tan. B.; Hernández-Torres, G.; Barbas III, C. F. Rational Design Enables Amide Nucleophiles for Organocatalytic Asymmetric Michael Reactions. Angew. Chem. Int. Ed. 2012, 51, 5381-5385.

4.      Tan B.; Hernández-Torres, G.; Barbas III, C. F. Highly Efficient Hydrogen-Bonding Catalysis of the Diels-Alder Reaction of 3-Vinylindoles and Methyleneindolinones Provides Carbazolespirooxindole Skeleton. J. Am. Chem. Soc. 2011, 131, 12354-12358.

5.      Tan, B.; Candeias, N.; Barbas III, C. F. Core-Structure-Motivated Design of a Phosphine-Catalyzed [3+2] Cycloaddition Reaction: Enantioselective Syntheses of Spirocyclopenteneoxindoles. J. Am. Chem. Soc. 2011, 131, 4672-4675.

6.      Tan, B.; Shi. Z.; Chua, P. J.; Li, Y.; Zhong, G. Unusual Domino Michael/Aldol Condensation Reactions Employing Oximes as N-Selective Nucleophiles: Synthesis of N-Hydroxypyrroles. Angew. Chem. Int. Ed. 2009, 48, 758-761.

 

代表性研究成果:(独立工作以后从20138月至今)

1. Jin-Hui Xu, Sheng-Cai Zheng, Ji-Wei Zhang and Bin Tan*. Organocatalytic Asymmetric Dearomatization of Isoquinolines Enables Construction of Tropane Derivatives. Angew. Chem. Int. Ed. 2016, 55, DOI: 10.1002/anie.201605736R1.

2. Ji-Wei Zhang, Jin-Hui Xu, Dao-Juan Cheng, Chuan Shi, Xin-Yuan Liu* and Bin Tan*. Discovery and Enantiocontrol of Axially Chiral Urazoles via Organocatalytic Tyrosine Click Reaction. Nature Communications, 2016, 7, 10677. DOI: 10.1038/ncomms10677.

3. Ye-Hui Chen, Dao-Juan Cheng, Jian Zhang, Yong Wang, Xin-Yuan Liu*, and Bin Tan*. Atroposelective Synthesis of Axially Chiral Biaryldiols via Organocatalytic Arylation of 2‑Naphthols. J. Am. Chem. Soc. 2015, 137, 15062.

4. Jian Zhang, Shao-Xia Lin, Dao-Juan Cheng, Xin-Yuan Liu,* and Bin Tan*. Phosphoric Acid-Catalyzed Asymmetric Classic Passerini Reaction. J. Am. Chem. Soc. 2015, 137, 14039.

5. Ming-Yue Wu, Wei-Wei He, Xin-Yuan Liu*, Bin Tan*. Asymmetric Construction of Spirooxindoles by Organocatalytic Multicomponent Reactions Using Diazooxindoles. Angew. Chem. Int. Ed. 2015, 54, 9409.

6. Zhi-Jia Fang, Sheng-Cai Zheng, Zhen Guo, Jing-Yao Guo, Bin Tan,* Xin-Yuan Liu*. Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation. Angew. Chem. Int. Ed. 2015, 54, 9528.

7. Jin-Shun Lin, Peng Yu, Lin Huang, Pan Zhang, Bin Tan,* Xin-Yuan Liu*. Brønsted Acid-Catalyzed Asymmetric Hydroamination of Alkenes: Synthesis of  Pyrrolidines Bearing a Tetrasubstituted Carbon Stereocenter. Angew. Chem. Int. Ed. 2015, 54, 7847.

8. Peng Yu, Sheng-Cai Zheng, Ning-Yuan Yang, Bin Tan,* Xin-Yuan Liu*. Phosphine-Catalyzed Remote β-C-H Functionalization of Amine Triggered by Trifluoromethylation of Alkene: One-Pot Synthesis of Bistrifluoromethylated Enamides and Oxazoles. Angew. Chem. Int. Ed. 2015, 54, 4041.

9. Peng Yu, Jin-Shun Lin, Lei Li, Sheng-Cai Zheng, Ya-Ping Xiong, Li-Jiao Zhao, Bin Tan*, and Xin-Yuan Liu*. Enantioselective C-H Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated Alkene.  Angew. Chem. Int. Ed. 2014, 53, 11890.

10. Dao-Juan Cheng, Liang Yan, Shi-Kai Tian,* Ming-Yue Wu, Lu-Xin Wang, Zi-Li Fan, Sheng-Cai Zheng, Xin-Yuan Liu,* and Bin Tan*. Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid. Angew. Chem. Int. Ed. 2014, 53, 3684.

 

11. Lin Huang, Jin-Shun Lin, Bin Tan,* and Xin-Yuan Liu*. Alkene Trifluoromethylation-Initiated Remote α-Azidation of Carbonyl Compounds toward Trifluoromethyl γ-Lactam and Spirobenzofuranone-lactam. ACS Catal. 2015, 5, 2826.

 

 

12. Lin Huang, Sheng-Cai Zheng, Bin Tan,* Xin-Yuan Liu*, Metal-Free Direct 1,6- and 1,2-Difunctionalization Triggered by Radical Trifluoromethylation of Alkenes. Org. Lett. 2015, 17, 1589-1592.

 

13. Lin Huang, Sheng-Cai Zheng, Bin Tan,* Xin-Yuan Liu*, Trifluoromethylation-Initiated Remote Cross-Coupling of Carbonyl Compounds to Form Carbon–Heteroatom/Carbon Bonds. Chem. Eur. J. 2015, 21, 6718.

 

14. Lei Li, Jing-Yao Guo, Su Chen, Tao Wang, Bin Tan* and Xin-Yuan Liu* “Amide Groups Switch Selectivity: C-H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation” Org. Lett., 2014, 16, 6032.

 

15. Jin-Shun Lin, Xiang-Geng Liu, Xiao-Long Zhu, Bin Tan* and Xin-Yuan Liu* “Copper-Catalyzed Aminotrifluoromethylation of Unactivated Alkenes with TMSCF3: Construction of Trifluoromethylated Azaheterocycles” J. Org. Chem. 2014, 79, 7084.

 

16. Xing-Li Zhu, Jin-Hui Xu, Dao-Juan Cheng, Li-Jiao Zhao, Xin-Yuan Liu* and Bin Tan* “In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles” Org. Lett. 2014, 16, 2192.

 

17. Ya-Ping Xiong, Ming-Yue Wu, Xiang-Yu Zhang, Can-Liang Ma, Lin Huang, Li-Jiao Zhao, Bin Tan* and Xin-Yuan Liu* “Direct Access to α-CF3-enones via Efficient Copper-Catalyzed Trifluoromethylation of Meyer-Schuster Rearrangement” Org. Lett. 2014, 16, 1000.

 

18. Lei Li, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Bin Tan* and Xin-Yuan Liu.* “Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles” Org. Lett. 2014, 16, 504.

 

19. Jin-Shun Lin, Ya-Ping Xiong, Can-Liang Ma, Li-Jiao Zhao, Bin Tan* and Xin-Yuan Liu*. “Efficient Copper-Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen-Based Nucleophiles” Chem. Eur. J. 2014, 20, 1332.

20. Dao-Juan Cheng, Yoshihiro Ishihara, Bin Tan* and Carlos F. Barbas, III*. Organocatalytic Asymmetric Assembly Reactions: Synthesis of Spirooxindoles via Organocascade Strategies. ACS Catal. 2014, 4, 743.

 

 

正在审稿和准备投稿的论文:

1. Lei Li, Zhong-Liang Li, Fu-Li Wang, Zhen Guo, Yong-Feng Cheng, Na Wang, Chao Fang, Jingjiang Liu, Chunhui Hou, Bin Tan,* and Xin-Yuan Liu*. Radical Aryl/Vinyl Migration Enables Diversity-Oriented Synthesis of Structurally Diverse Medium/Macro- or Bridged-Rings. Nature Chem. 2016, under revision.

 

2. Shao-Yu Li, Ji-Wei Zhang, Xian-Lin Li, and Bin Tan*. Phosphoric Acid-Catalyzed Atroposelective Synthesis of SPINOL Derivatives. J. Am. Chem. Soc. 2016, under review.

 

3. Sheng-Cai Zheng, San Wu, Yun-Hao Zhang, Liu Ye and Bin Tan*. Organocatalytic Atropselective Synthesis of Axially Chiral Styrenes. J. Am. Chem. Soc. 2016, under review.

 

4. Lei Zhang, Ji-Ma and Bin Tan*. Brønsted Acid-Catalyzed Atropselective Paal-Knorr Reaction. J. Am. Chem. Soc. 2016, to be submitted.

 

5. Yong-Bin Wang, Ji-Wei Zhang and BinTan*. Atropselective Synthesis of Quinazolinones via Organocatalysis. Angew. Chem. Int. Ed. 2016, to be submitted.

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